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If the cellular mechanisms to scavenge ROS are inadequate, they can trigger free radical chain reactions that further damage proteins, lipids, and nucleic acids, potentially leading to various disease conditions (Craft et al

These distinct features cause some organs, such as the brain, to be susceptible to oxidative injury

[DOI] [PubMed] [Google Scholar] 41.Gomez-Sanchez EP, Gomez-Sanchez CE

Importantly, GSH itself does not spontaneously sequester hydroperoxides since the reaction kinetics are far too slow (30 M 1 s 1 ) (Berndt et al., 2 O 2 and lipid hydroperoxides or participate in covalent modification of protein cysteine thiols depends on various enzymes that specifically bind glutathione to catalyze redox reactions (Flohe, 2013